Synthesis, structure and coordination chemistry of mono- and bis-heterocyclic-ferrocenyl derivatives

被引：26

作者：

Isaac, CJ ^{[1
]}

Price, C ^{[1
]}

Horrocks, BR ^{[1
]}

Houlton, A ^{[1
]}

Elsegood, MRJ ^{[1
]}

Clegg, W ^{[1
]}

机构：

[1] Newcastle Univ, Dept Chem, Crystallog Lab, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2000年 / 598卷 / 02期

关键词：

ferrocenyl; heterocyclic; palladium;

D O I：

10.1016/S0022-328X(99)00717-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The heterocyclic-ferrocenyl derivatives, 1,1'-bis(5-phenanthridine)ferrocene (1) and [Pd{(eta(5)-C5H5)Fe(eta(5)-C5H3(phenanthroline))Cl] (2), have been prepared and characterised by single-crystal X-ray analyses. These confirm that in 1 the substitution at the heterocycle is ortho to the nitrogen atom of the phenanthridine while for 2 artho-metallation of the ferrocenyl group is observed in addition to chelation of the Pd(II) by the phenanthroline moiety. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：248 / 253

页数：6

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