Sequential extraction for radionuclide fractionation in soil samples:: a comparative study

被引:40
作者
Blanco, P
Tomé, FV
Lozano, JC
机构
[1] Univ Extremadura, Fac Ciencias, Dept Fis, E-06071 Badajoz, Spain
[2] Univ Salamanca, Fac Ciencias, Lab Radiactividad Ambiental, Salamanca 37008, Spain
关键词
alpha spectrometry; sequential extraction; natural radionuclides; reproducibility;
D O I
10.1016/j.apradiso.2004.03.006
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two sequential extraction procedures, Tessier's method (Anal. Chem. 51(7) (1979) 844), and a current version known as Schultz's method (J. Environ. Radioact. 40(2) (1998) 155), were compared. The two procedures were applied to a natural soil sample that presents high activity concentrations in natural radionuclides of the U-238 series. Reproducibility studies of each method and a comparison between the two sets of results were performed for uranium, thorium, and radium. The results were different for each radionuclide. Analysis of the extracted fractions was carried out by alpha spectrometry. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:345 / 350
页数:6
相关论文
共 17 条
[1]   Heavy metal levels and solid phase speciation in street dusts of Delhi, India [J].
Banerjee, ADK .
ENVIRONMENTAL POLLUTION, 2003, 123 (01) :95-105
[2]   On the use of 225Ra as yield tracer and Ba(Ra)SO4 microprecipitation in 226Ra determination by α-spectrometry [J].
Blanco, P ;
Lozano, JC ;
Tomé, FV .
APPLIED RADIATION AND ISOTOPES, 2002, 57 (06) :785-790
[3]   Determination of radionuclide exchangeability in freshwater systems [J].
Bunker, DJ ;
Smith, JT ;
Livens, FR ;
Hilton, J .
SCIENCE OF THE TOTAL ENVIRONMENT, 2000, 263 (1-3) :171-183
[4]   MECHANISMS OF TRACE METAL TRANSPORT IN RIVERS [J].
GIBBS, RJ .
SCIENCE, 1973, 180 (4081) :71-73
[5]   Fractionation studies of trace elements in contaminated soils and sediments: a review of sequential extraction procedures [J].
Gleyzes, C ;
Tellier, S ;
Astruc, M .
TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 2002, 21 (6-7) :451-467
[6]  
GRUPTA SK, 1975, ENVIRON LETT, V10, P129
[8]   Evaluation of remediation process with plant-derived biosurfactant for recovery of heavy metals from contaminated soils [J].
Hong, KJ ;
Tokunaga, S ;
Kajiuchi, T .
CHEMOSPHERE, 2002, 49 (04) :379-387
[9]   DETERMINATION OF THORIUM, URANIUM AND PLUTONIUM ISOTOPES IN ATMOSPHERIC SAMPLES [J].
JIANG, FS ;
LEE, SC ;
BAKHTIAR, SN ;
KURODA, PK .
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY-ARTICLES, 1986, 100 (01) :65-72
[10]   Reproducibility testing of a sequential extraction scheme for the determination of trace metal speciation in a marine reference sediment by inductively coupled plasma-mass spectrometry [J].
Marin, B ;
Valladon, M ;
Polve, M ;
Monaco, A .
ANALYTICA CHIMICA ACTA, 1997, 342 (2-3) :91-112