Temperature Dependence of Sol-Gel Conversion Kinetics in Gelatin-Water System

被引：55

作者：

Chen, Kai ^{[1
]}

Vyazovkin, Sergey ^{[1
]}

机构：

[1] Univ Alabama Birmingham, Dept Chem, Birmingham, AL 35294 USA

来源：

MACROMOLECULAR BIOSCIENCE | 2009年 / 9卷 / 04期

关键词：

activation energy; biopolymers; differential scanning calorimetry (DSC); gelation; kinetics (polym.); ACTIVATION-ENERGY; PHASE-SEPARATION; HYDROXYAPATITE; CHITOSAN; CRYSTALLIZATION; TRANSITIONS; APATITE;

D O I：

10.1002/mabi.200800214

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The conversion kinetics of an aqueous gelatin solution to gel was studied by temperature modulated and regular DSC under isothermal and continuous cooling conditions. isothermal runs revealed a decrease in the quasi-static heat capacity primarily associated with syneresis (phase senaration) of the gel. Above 19 degrees C the isothermal process demonstrated negative effective activation energy that turned positive below 14 degrees C. Continuous cooling runs detected a reversing heat flow apparently related to the continuing formation and melting of new gel structures. Isoconversional kinetic analysis of continuous cooling measurements yielded negative activation energy for the whole range of conversions and temperatures suggesting that nucleation remained a rate controlling step throughout the whole gelation process.

引用

页码：383 / 392

页数：10

共 44 条

[1] Towards biologically inspired materials [J].

Babini, GN ;

Tampieri, A .

BRITISH CERAMIC TRANSACTIONS, 2004, 103 (03) :101-109

[2] Bonelike apatite growth on hydroxyapatite-gelatin sponges from simulated body fluid [J].

Bigi, A ;

Boanini, E ;

Panzavolta, S ;

Roveri, N ;

Rubini, K .

JOURNAL OF BIOMEDICAL MATERIALS RESEARCH, 2002, 59 (04) :709-715

[3] Kinetics of gelatin transitions with phase separation:: T-jump and step-wise DSC study [J].

Cuppo, F ;

Venuti, M ;

Cesàro, A .

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2001, 28 (04) :331-341

[4]

de Gennes P.G., 1985, SCALING CONCEPTS POL, V2

[5] GELATION OF AQUEOUS GELATIN SOLUTIONS .1. STRUCTURAL INVESTIGATION [J].

DJABOUROV, M ;

LEBLOND, J ;

PAPON, P .

JOURNAL DE PHYSIQUE, 1988, 49 (02) :319-332

[6]

Eagland D, 1974, Faraday Discuss Chem Soc, P181, DOI 10.1039/dc9745700181

[7] Macroporous styrene-divinylbenzene copolymers: Formation of stable porous structures during the copolymerization [J].

Erbay, E ;

Okay, O .

POLYMER BULLETIN, 1998, 41 (03) :379-385

[8] Preparation and morphology study of microporous poly(HEMA-MMA) particles [J].

Fang, Dongyu ;

Pan, Qinmin ;

Rempel, Garry L. .

JOURNAL OF APPLIED POLYMER SCIENCE, 2007, 103 (02) :707-715

[9] Helix reversible arrow coil transitions in dilute aqueous collagen solutions [J].

Flory, Paul J. ;

Weaver, Edwin S. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (17) :4518-4525

[10] GENERAL TREATMENT OF THERMOGRAVIMETRY OF POLYMERS [J].

FLYNN, JH ;

WALL, LA .

JOURNAL OF RESEARCH OF THE NATIONAL BUREAU OF STANDARDS SECTION A-PHYSICS AND CHEMISTRY, 1966, A 70 (06) :487-+

← 1 2 3 4 5 →