Dielectric relaxation of the quantum nanomagnet Mn12 acetate

被引:13
作者
Kutnjak, Z
Filipic, C
Levstik, A
Achey, RM
Dalal, NS
机构
[1] Jozef Stefan Inst, Ljubljana 1001, Slovenia
[2] Florida State Univ, Dept Chem, Tallahassee, FL 32310 USA
[3] Florida State Univ, Natl High Magnet Field Lab, Tallahassee, FL 32310 USA
来源
PHYSICAL REVIEW B | 1999年 / 59卷 / 17期
关键词
D O I
10.1103/PhysRevB.59.11147
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The temperature- and frequency-dependent dielectric relaxation in the quantum nanomagnet Mn-12 acetate and its partially and fully deuterated analogs has been investigated. The four distinct dielectric modes following an activated behavior have been identified in the temperature range from 300-2.8 K and frequency window of 20 Hz-1 MHz. Analysis of the dielectric data in partially and fully deuterated Mn-12 acetate indicates that the three slowest modes can be ascribed to the motion of H2O while the fourth mode to that of the CH3 groups. [S0163-1829(99)09817-3].
引用
收藏
页码:11147 / 11150
页数:4
相关论文
共 23 条
[1]   Deuteron spin-lattice relaxation in the Mn12O12-acetate magnetic cluster [J].
Arcon, D ;
Dolinsek, J ;
Apih, T ;
Blinc, R ;
Dalal, NS ;
Achey, RM .
PHYSICAL REVIEW B, 1998, 58 (06) :R2941-R2943
[2]   ALTERNATING-CURRENT SUSCEPTIBILITY, HIGH-FIELD MAGNETIZATION, AND MILLIMETER BAND EPR EVIDENCE FOR A GROUND S = 10 STATE IN [MN12O12(CH3COO)16(H2O)4].2CH3COOH.4H2O [J].
CANESCHI, A ;
GATTESCHI, D ;
SESSOLI, R ;
BARRA, AL ;
BRUNEL, LC ;
GUILLOT, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (15) :5873-5874
[3]   Dispersion and absorption in dielectrics I. Alternating current characteristics [J].
Cole, KS ;
Cole, RH .
JOURNAL OF CHEMICAL PHYSICS, 1941, 9 (04) :341-351
[4]   Deuteron NMR of a manganese-ion cluster nanomagnet [J].
Dolinsek, J ;
Arcon, D ;
Blinc, R ;
Vonlanthen, P ;
Gavilano, JL ;
Ott, HR ;
Achey, RM ;
Dalal, NS .
EUROPHYSICS LETTERS, 1998, 42 (06) :691-694
[5]   Macroscopic measurement of resonant magnetization tunneling in high-spin molecules [J].
Friedman, JR ;
Sarachik, MP ;
Tejada, J ;
Ziolo, R .
PHYSICAL REVIEW LETTERS, 1996, 76 (20) :3830-3833
[6]   LARGE CLUSTERS OF METAL-IONS - THE TRANSITION FROM MOLECULAR TO BULK MAGNETS [J].
GATTESCHI, D ;
CANESCHI, A ;
PARDI, L ;
SESSOLI, R .
SCIENCE, 1994, 265 (5175) :1054-1058
[7]   Specific heat and magnetic relaxation of the quantum nanomagnet Mn12Ac [J].
Gomes, AM ;
Novak, MA ;
Sessoli, R ;
Caneschi, A ;
Gatteschi, D .
PHYSICAL REVIEW B, 1998, 57 (09) :5021-5024
[8]  
Gunther L., 1995, NATO ASI E
[9]   Neutron study of mesoscopic magnetic clusters: Mn12O12 [J].
Hennion, M ;
Pardi, L ;
Mirebeau, I ;
Suard, E ;
Sessoli, R ;
Caneschi, A .
PHYSICAL REVIEW B, 1997, 56 (14) :8819-8827
[10]   Field tuning of thermally activated magnetic quantum tunnelling in Mn-12-Ac molecules [J].
Hernandez, JM ;
Zhang, XX ;
Luis, F ;
Bartolome, J ;
Tejada, J ;
Ziolo, R .
EUROPHYSICS LETTERS, 1996, 35 (04) :301-306