All-polymer solar cells based on a blend of poly[3-(10-n-octyl-3-phenothiazine-vinylene)thiophene-co-2,5-thiophene] and poly[1,4-dioctyloxyl-p-2,5-dicyanophenylenevinylene]

被引:42
作者
Sang, Guangyi [1 ,2 ]
Zou, Yingping [1 ]
Huang, Yu [1 ,2 ]
Zhao, Guangjin [1 ,2 ]
Yang, Yi [1 ,2 ]
Li, Yongfang [1 ]
机构
[1] Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Organ Solids, Inst Chem, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China
关键词
annealing; charge exchange; photoluminescence; polymer blends; power conversion; solar cells; PHOTOVOLTAIC PROPERTIES; MDMO-PPV; NETWORK; CHARGE;
D O I
10.1063/1.3134490
中图分类号
O59 [应用物理学];
学科分类号
摘要
We report all-polymer solar cells (PSCs) based on a polymer blend of poly[3-(10-n-octyl-3-phenothiazine-vinylene)thiophene-co-2,5-thiophene] as donor and poly[1,4-dioctyloxyl-p-2,5-dicyanophenylenevinylene] as acceptor. Strong photoluminescence quenching is observed in the polymer blend indicating the photoinduced charge transfer occurs between the two polymers. The power conversion efficiency of the PSC was improved from 0.41% to 0.8% after 120 degrees C postannealing, under the illumination of AM 1.5, 100 mW/cm(2). We attribute the improved efficiency to better morphological features of the photoactive layer after thermal annealing.
引用
收藏
页数:3
相关论文
共 23 条
[1]   Laminated fabrication of polymeric photovoltaic diodes [J].
Granström, M ;
Petritsch, K ;
Arias, AC ;
Lux, A ;
Andersson, MR ;
Friend, RH .
NATURE, 1998, 395 (6699) :257-260
[2]   Conjugated polymer-based organic solar cells [J].
Guenes, Serap ;
Neugebauer, Helmut ;
Sariciftci, Niyazi Serdar .
CHEMICAL REVIEWS, 2007, 107 (04) :1324-1338
[3]   Charge- and energy-transfer processes at polymer/polymer interfaces:: A joint experimental and theoretical study [J].
Halls, JJM ;
Cornil, J ;
dos Santos, DA ;
Silbey, R ;
Hwang, DH ;
Holmes, AB ;
Brédas, JL ;
Friend, RH .
PHYSICAL REVIEW B, 1999, 60 (08) :5721-5727
[4]   Synthesis, Characterization, and Photovoltaic Properties of a Low Band Gap Polymer Based on Silole-Containing Polythiophenes and 2,1,3-Benzothiadiazole [J].
Hou, Jianhui ;
Chen, Hsiang-Yu ;
Zhang, Shaoqing ;
Li, Gang ;
Yang, Yang .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (48) :16144-+
[5]   INVESTIGATION OF CURRENT FLOW IN HIGH-TEMPERATURE SUPERCONDUCTING THICK-FILMS [J].
JONES, AR ;
BAKER, AP ;
DEWHURST, CD ;
ASHWORTH, SP ;
CARDWELL, DA ;
CAMPBELL, AM .
APPLIED SUPERCONDUCTIVITY, 1995, 3 (1-3) :47-53
[6]   Efficient polymer solar cells based on M3EH-PPV [J].
Kietzke, T ;
Hörhold, HH ;
Neher, D .
CHEMISTRY OF MATERIALS, 2005, 17 (26) :6532-6537
[7]   Efficient polymer:polymer bulk heterojunction solar cells [J].
Koetse, MM ;
Sweelssen, J ;
Hoekerd, KT ;
Schoo, HFM ;
Veenstra, SC ;
Kroon, JM ;
Yang, XN ;
Loos, J .
APPLIED PHYSICS LETTERS, 2006, 88 (08)
[8]   High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends [J].
Li, G ;
Shrotriya, V ;
Huang, JS ;
Yao, Y ;
Moriarty, T ;
Emery, K ;
Yang, Y .
NATURE MATERIALS, 2005, 4 (11) :864-868
[9]   Thermally stable, efficient polymer solar cells with nanoscale control of the interpenetrating network morphology [J].
Ma, WL ;
Yang, CY ;
Gong, X ;
Lee, K ;
Heeger, AJ .
ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (10) :1617-1622
[10]   Origin of the reduced fill factor and photocurrent in MDMO-PPV:PCNEPV all-polymer solar cells [J].
Mandoc, M. Magdalena ;
Veurman, Welmoed ;
Koster, L. Jan Anton ;
de Boer, Bert ;
Blom, Paul W. M. .
ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (13) :2167-2173