Chemical reaction dynamics at liquid interfaces: A computational approach

被引：14

作者：

Benjamin, I ^{[1
]}

机构：

[1] Univ Calif Santa Cruz, Dept Chem, Santa Cruz, CA 95064 USA

来源：

PROGRESS IN REACTION KINETICS AND MECHANISM | 2002年 / 27卷 / 02期

关键词：

computer simulations; liquid interfaces; surface roughness; polarity; isomerization; electron transfer; photodissociation;

D O I：

10.3184/007967402103165360

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Recent advances in experimental and theoretical studies of liquid interfaces provide remarkable evidence for the unique properties of these systems. In this review we examine how these properties affect the thermodynamics and kinetics of chemical reactions which take place at the liquid/vapor interface and at the liquid/liquid interface. We demonstrate how the rapidly varying density and viscosity, the marked changes in polarity and the surface roughness manifest themselves in isomerization, electron transfer and photodissociation reactions.

引用

页码：87 / 126

页数：40

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