Rotational Feshbach resonances in ultracold molecular collisions

被引:31
作者
Bohn, JL [1 ]
Avdeenkov, AV
Deskevich, MP
机构
[1] Univ Colorado, Joint Inst Lab Astrophys, Boulder, CO 80309 USA
[2] Univ Colorado, Dept Phys, Boulder, CO 80309 USA
[3] Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA
关键词
D O I
10.1103/PhysRevLett.89.203202
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
In collisions at ultralow temperatures, molecules will possess Feshbach resonances, foreign to ultracold atoms, whose virtual excited states consist of rotations of the molecules. We estimate the mean spacing and mean widths of these resonant states, exploiting the fact the molecular collisions at low energy display chaotic motion. As examples, we consider the experimentally relevant molecules O-2, OH, and PbO. Especially for polar species, the density of s-wave resonant states is quite high, implying potentially disastrous consequences for trapped molecules.
引用
收藏
页码:203202 / 203202
页数:4
相关论文
共 31 条
[1]   A CLASSICAL TRAJECTORY STUDY OF AR+AR2 COLLISIONS - PHASE-SPACE STRUCTURES IN 3 DEGREES OF FREEDOM [J].
ATKINS, KM ;
HUTSON, JM .
JOURNAL OF CHEMICAL PHYSICS, 1995, 103 (21) :9218-9227
[2]   Ultracold collisions of oxygen molecules [J].
Avdeenkov, AV ;
Bohn, JL .
PHYSICAL REVIEW A, 2001, 64 (05) :10
[3]   Chemistry at ultracold temperatures [J].
Balakrishnan, N ;
Dalgarno, A .
CHEMICAL PHYSICS LETTERS, 2001, 341 (5-6) :652-656
[4]   Deceleration and trapping of ammonia using time-varying electric fields [J].
Bethlem, HL ;
Crompvoets, FMH ;
Jongma, RT ;
van de Meerakker, SYT ;
Meijer, G .
PHYSICAL REVIEW A, 2002, 65 (05) :20
[5]   Observation of a Feshbach resonance in cold atom scattering [J].
Courteille, P ;
Freeland, RS ;
Heinzen, DJ ;
van Abeelen, FA ;
Verhaar, BJ .
PHYSICAL REVIEW LETTERS, 1998, 81 (01) :69-72
[7]   Investigation of PbO as a system for measuring the electric dipole moment of the electron [J].
DeMille, D ;
Bay, F ;
Bickman, S ;
Kawall, D ;
Krause, D ;
Maxwell, SE ;
Hunter, LR .
PHYSICAL REVIEW A, 2000, 61 (05) :8
[8]   EFFECT OF CLOSED CLASSICAL ORBITS ON QUANTUM SPECTRA - IONIZATION OF ATOMS IN A MAGNETIC-FIELD .2. DERIVATION OF FORMULAS [J].
DU, ML ;
DELOS, JB .
PHYSICAL REVIEW A, 1988, 38 (04) :1913-1930
[9]   EFFECT OF CLOSED CLASSICAL ORBITS ON QUANTUM SPECTRA - IONIZATION OF ATOMS IN A MAGNETIC-FIELD .1. PHYSICAL PICTURE AND CALCULATIONS [J].
DU, ML ;
DELOS, JB .
PHYSICAL REVIEW A, 1988, 38 (04) :1896-1912
[10]   STATISTICAL THEORY OF ENERGY LEVELS OF COMPLEX SYSTEMS .4. [J].
DYSON, FJ ;
MEHTA, ML .
JOURNAL OF MATHEMATICAL PHYSICS, 1963, 4 (05) :701-&