Carbon-nanotube-templated and pseudorotaxane-formation-driven gold nanowire self-assembly

被引:56
作者
Sainsbury, T [1 ]
Fitzmaurice, D [1 ]
机构
[1] Natl Univ Ireland Univ Coll Dublin, Dept Chem, Dublin 4, Ireland
关键词
D O I
10.1021/cm035368k
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A cation-modified multiwalled carbon nanotube is used to template the noncovalent selfassembly in solution of a gold nanowire from crown-modified gold nanoparticles. The driving force for self-assembly is formation of the surface-confined pseudorotaxane that results from the electron-poor cation threading the electron-rich crown.
引用
收藏
页码:2174 / 2179
页数:6
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