Thermal Stabilisation of Polymer-Fullerene Bulk Heterojunction Morphology for Effi cient Photovoltaic Solar Cells

被引:153
作者
Derue, Lionel [1 ]
Dautel, Olivier [2 ]
Tournebize, Aurelien [3 ]
Drees, Martin [7 ,8 ]
Pan, Hualong [7 ,8 ]
Berthumeyrie, Sebastien [3 ]
Pavageau, Bertrand [6 ]
Cloutet, Eric [4 ]
Chambon, Sylvain [1 ]
Hirsch, Lionel [1 ]
Rivaton, Agnes [3 ]
Hudhomme, Pietrick [5 ]
Facchetti, Antonio [7 ,8 ]
Wantz, Guillaume [1 ]
机构
[1] Univ Bordeaux, IMS Lab, F-33607 Pessac, France
[2] Charles Gerhardt Inst, AM2N Lab, F-34296 Montpellier, France
[3] Univ Blaise Pascal, ICCF Lab, F-63000 Clermont Ferrand, France
[4] Univ Bordeaux, LCPO Lab, F-33607 Pessac, France
[5] Univ Angers, MOLTECH Anjou, F-49045 Angers, France
[6] Solvay, LoF Lab, Pessac, France
[7] POLYERA Corp, Skokie, IL 60077 USA
[8] King Abdulaziz Univ, CEAMR, Jeddah 21413, Saudi Arabia
关键词
organic photovoltaic; crystallization; morphology stabilization; cross-linking; INTERNAL QUANTUM EFFICIENCY; FUNCTIONALIZED POLYTHIOPHENE; PERFORMANCE; ORGANIZATION; BISADDUCT; BLENDS;
D O I
10.1002/adma.201401062
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel stable bisazide molecule that can freeze the bulk heterojunction morphology at its optimized layout by specifically bonding to fullerenes is reported. The concept is demonstrated with various polymers: fullerene derivatives systems enable highly thermally stable polymer solar cells. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:5831 / 5838
页数:8
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