Preparation of magnetic polystyrene latex via the miniemulsion polmerization technique

Magnetic iron oxide (magnetite, Fe3O4) nanoparticles were encapsulated with polystyrene to give a stable water-based magnetic polymer latex, using the miniemulsion polymerization technique. The resulting magnetic latexes were characterized with transmission electron microscopy (TEM), dynamic light scattering (DLS), vibrating sample magnetometer measurements (VSM), and Fe-57 Mossbauer spectroscopy measurements. TEM revealed that all magnetite nanoparticles were embedded in the polymer spheres, leaving no empty polystyrene particles. The distribution of magnetite particles within the polystyrene spheres was inhomogeneous, showing an uneven polar appearance. The DLS measurements indicated a bimodal size distribution for the particles in the latexes. According to our magnetometry and Mossbauer spectroscopy data, the encapsulated magnetite particles conserve their superparamagnetic feature when they are separated in the polymer matrix. (C) 2004 Wiley Periodicals, Inc.