Experimental and computational study of a reductive elimination mechanism in a methyl-Pd(II)-CNC carbene complex

被引：61

作者：

Nielsen, DJ

Magill, AM

Yates, BF

Cavell, KJ

Skelton, BW

White, AH

机构：

[1] Univ Tasmania, Hobart, Tas 7005, Australia

[2] Cardiff Univ, Dept Chem, Cardiff CF10 3TB, S Glam, Wales

[3] Univ Western Australia, Crawley, WA 6009, Australia

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 21期

关键词：

D O I：

10.1039/b207020k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Experimental and density functional studies on the decomposition of a novel palladium-methyl complex of the rigid CNC ligand 2,6-bis(1-alkylimidazolin-2-yliden-3-yl)pyridine show that reductive elimination to give 2-methylimidazolium species is a facile reaction.

引用

页码：2500 / 2501

页数：2

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