Examining CDOM fluorescence variability using principal component analysis: seasonal and regional modeling of three-dimensional fluorescence in the Gulf of Mexico

被引:64
作者
Boehme, J
Coble, P
Conmy, R
Stovall-Leonard, A
机构
[1] Univ Maine, Darling Marine Ctr, Walpole, ME 04573 USA
[2] Univ S Florida, Coll Marine Sci, St Petersburg, FL 33701 USA
关键词
dissolved organic matter; fluorescence; principal component analysis; USA; Gulf of Mexico;
D O I
10.1016/j.marchem.2004.03.019
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Alterations in colored dissolved organic matter (CDOM) characteristics were examined for an extensive fluorescence data set generated by excitation emission matrix spectroscopy (EEMS). Principal component analysis (PCA) was used to assess changes in fluorescence bandwidth and wavelength shifts of entire peak regions, enhancing previous CDOM characterization that was based on changes observed at a few excitation and emission wavelength pairs. Variability within the data set is expressed as a series of linear terms, which can be used to quantitatively evaluate changes in CDOM fluorescence within the perspective of a single cruise or a large geographic region. In this paper we will present PCA results from a comprehensive fluorescence data set examining seasonal and regional CDOM variability within the Gulf of Mexico. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:3 / 14
页数:12
相关论文
共 22 条
[1]  
BENAGIANO G, 1994, INT J GYNECOL OBSTET, V46, P1
[2]   Characterization of colored dissolved organic matter using high-energy laser fragmentation [J].
Boehme, JR ;
Coble, PG .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2000, 34 (15) :3283-3290
[3]  
BOEHME JR, 2003, THESIS U S FLORIDA T
[4]   SYNCHRONOUS FLUORESCENCE-SPECTRA OF NATURAL-WATERS - TRACING SOURCES OF DISSOLVED ORGANIC-MATTER [J].
CABANISS, SE ;
SHUMAN, MS .
MARINE CHEMISTRY, 1987, 21 (01) :37-50
[5]   THE FLUORESCENCE OF DISSOLVED ORGANIC-MATTER IN SEAWATER [J].
CHEN, RF ;
BADA, JL .
MARINE CHEMISTRY, 1992, 37 (3-4) :191-221
[6]   THE FLUORESCENCE OF DISSOLVED ORGANIC-MATTER IN POREWATERS OF MARINE-SEDIMENTS [J].
CHEN, RF ;
BADA, JL .
MARINE CHEMISTRY, 1994, 45 (1-2) :31-42
[7]   FLUORESCENCE CONTOURING ANALYSIS OF DOC INTERCALIBRATION EXPERIMENT SAMPLES - A COMPARISON OF TECHNIQUES [J].
COBLE, PG ;
SCHULTZ, CA ;
MOPPER, K .
MARINE CHEMISTRY, 1993, 41 (1-3) :173-178
[8]   CHARACTERIZATION OF DISSOLVED ORGANIC-MATTER IN THE BLACK-SEA BY FLUORESCENCE SPECTROSCOPY [J].
COBLE, PG ;
GREEN, SA ;
BLOUGH, NV ;
GAGOSIAN, RB .
NATURE, 1990, 348 (6300) :432-435
[9]   Characterization of marine and terrestrial DOM in seawater using excitation emission matrix spectroscopy [J].
Coble, PG .
MARINE CHEMISTRY, 1996, 51 (04) :325-346
[10]   Distribution and optical properties of CDOM in the Arabian Sea during the 1995 Southwest Monsoon [J].
Coble, PG ;
Del Castillo, CE ;
Avril, B .
DEEP-SEA RESEARCH PART II-TOPICAL STUDIES IN OCEANOGRAPHY, 1998, 45 (10-11) :2195-2223