A solid-supported phosphine-free ruthenium alkylidene for olefin metathesis in methanol and water

被引：110

作者：

Connon, SJ ^{[1
]}

Blechert, S ^{[1
]}

机构：

[1] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany

来源：

BIOORGANIC & MEDICINAL CHEMISTRY LETTERS | 2002年 / 12卷 / 14期

关键词：

D O I：

10.1016/S0960-894X(02)00260-3

中图分类号：

R914 [药物化学];

学科分类号：

100701 ;

摘要：

The synthesis and olefin metathesis activity in protic solvents of 7, a phosphine-free ruthenium alkylidene bound to a hydrophilic solid support are reported. This heterogeneous catalyst promotes relatively efficient ring closing- and cross-metathesis reactions in both methanol and water. The potential utility of homogeneous catalyst 2 for olefin metathesis in methanol is also demonstrated. (C) 2002 Elsevier Science Ltd. All rights reserved.

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页码：1873 / 1876

页数：4

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