Multiply charged clusters

被引:30
作者
Echt, O
Scheier, P
Märk, TD
机构
[1] Leopold Franzens Univ, Inst Ionenphys, A-6020 Innsbruck, Austria
[2] Univ New Hampshire, Dept Phys, Durham, NH 03824 USA
基金
奥地利科学基金会;
关键词
D O I
10.1016/S1631-0705(02)01325-7
中图分类号
P1 [天文学];
学科分类号
0704 ;
摘要
We review progress made in understanding Coulomb explosion of multiply charged atomic clusters. Their collision with highly charged atomic ions leads to clusters in charge states as high as z = 10 with little vibrational excess energy; these systems approach the Rayleigh limit. Phase transitions become evident at higher excess energies. Numerous studies have been devoted to C-60(z+) like collisions with surfaces, multi-coincidence fragmentation analysis and gas-phase reactions. Stability and decay of highly charged micrometer-sized droplets and of metal di- and trianions have been monitored in ion traps. Excitation by fermosecond laser pulses allows to unravel properties of highly charged transient cluster ions. (C) 2002 Academie des sciences/Editions scientifiques et medicales Elsevier SAS.
引用
收藏
页码:353 / 364
页数:12
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