Application of near infrared spectroscopy to rapid analysis of coals

被引:38
作者
Kaihara, M [1 ]
Takahashi, T [1 ]
Akazawa, T [1 ]
Sato, T [1 ]
Takahashi, S [1 ]
机构
[1] Ichinoseki Natl Coll Technol, Ichinoseki 0218511, Japan
关键词
coals; near infrared (NIR) spectroscopy; rapid analysis; PLS;
D O I
10.1081/SL-120005673
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
Comparing near infrared (NIR) spectra with infrared spectra in case of coal samples, we generally notice NIR spectra have less characteristic absorbance bands. However, utilizing merits of NIR spectroscopy (non destructive, high penetration ability, simple sample preparation, rapid analysis) and partial least squares regression (PLS) model, we found that several major properties of coals could be conveniently and rapidly estimated. For examples, multiple correlation coefficient between the measured values vs. the predicted values from obtained spectra, R-2, of moisture, volatile matter, oxygen content, maximum fluidity temperature, solidification temperature were 0.9736, 0.9774, 0.8996, 0.8849 and 0.9282 in respectively although the precision of obtained results were not superior to those by methods of American Standard of Testing Materials.
引用
收藏
页码:369 / 376
页数:8
相关论文
共 7 条
[1]   MATERIALS CHARACTERIZATION USING FACTOR-ANALYSIS OF FT-IR SPECTRA .1. RESULTS [J].
FREDERICKS, PM ;
LEE, JB ;
OSBORN, PR ;
SWINKELS, DAJ .
APPLIED SPECTROSCOPY, 1985, 39 (02) :303-310
[2]   LINEARIZATION AND SCATTER-CORRECTION FOR NEAR-INFRARED REFLECTANCE SPECTRA OF MEAT [J].
GELADI, P ;
MACDOUGALL, D ;
MARTENS, H .
APPLIED SPECTROSCOPY, 1985, 39 (03) :491-500
[3]  
Martens H, 1991, MULTIVARIATE CALIBRA
[4]  
MIKIO K, 1991, FUEL, V70, P931
[5]  
NORRIS KH, 1992, I MICHAEL PUBLICATIO
[6]   FT-IR ANALYSIS OF COAL .2. ALIPHATIC AND AROMATIC HYDROGEN CONCENTRATION [J].
SOLOMON, PR ;
CARANGELO, RM .
FUEL, 1988, 67 (07) :949-959
[7]  
1993, PENN STATE COAL SAMP