A heterodimetallic platinum-cobalt carboxylate complex PtIVCoII2(μ, η2-OOCCMe3)4(OOCCMe3)2(OH)2(HOOCCMe3)4:: Synthesis and structure

被引：5

作者：

Nefedov, Sergel E.

Kozitsyna, Natalia Yu.

Cherkashina, Natalia V.

Fukin, Georgy K.

Vargaftik, Michael N.

Moiseev, Ilya I.

机构：

[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

[2] Russian Acad Sci, GA Razuvaev Inst Organomet Chem, Nizhnii Novgorod 603950, Russia

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2006年 / 9卷 / 10期

基金：

俄罗斯基础研究基金会;

关键词：

platinum; cobalt; heterodimetallic complex; pivalate-bridging complex; X-ray structure;

D O I：

10.1016/j.inoche.2006.05.012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of the platinum(II,IV) acetate blue Pt(OOCMe)(2.5) with Co(OOCMe)(2) center dot 4H(2)O followed by acetate-pivalate ligand substitution gave the first Pt-IV-Co-II heterodimetallic purely carboxylate complex (PtCo2II)-Co-IV(mu,eta(2)- OOCCMe3)(4)(OOCCMe3)(2)(OH)(2)(HOOCCMe3)(4) with the [Pt(OOCCMe3)(4)] structure-forming building block as established by single-crystal X-ray diffraction study. (C) 2006 Elsevier B.V. All rights reserved.

引用

页码：1026 / 1028

页数：3

共 23 条

[1] SYNTHESIS AND STRUCTURE OF DINUCLEAR COMPLEXES OF PLATINUM(IV) HAVING CIS-DIAMINE GEOMETRY [J].