Spin transition in a chainlike supramolecular iron(II) complex

被引：69

作者：

Rajadurai, Chandrasekar

Schramm, Frank

Brink, Susan

Fuhr, Olaf

Ghafari, Mohamed

Kruk, Robert

Ruben, Mario

机构：

[1] Res Ctr Karlsruhe, Inst Nanotechnol, D-76021 Karlsruhe, Germany

[2] PAN, Inst Nucl Phys, PL-31342 Krakow, Poland

来源：

INORGANIC CHEMISTRY | 2006年 / 45卷 / 25期

关键词：

D O I：

10.1021/ic0612350

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A one-dimensional supramolecular head-to-tail N+-H center dot center dot center dot N-type hydrogen-bonded chain of the complex [Fe-II(L)(2)H](ClO4)(3)center dot MeOH [L = 4'-(4'''- pyridyl)-1,2':6'1''-bis(pyrazolyl)pyridine] exhibits a reversible, thermally driven spin transition at 286 K with a hysteresis loop of ca. 2 K.

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页码：10019 / 10021

页数：3

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