Enhancing heterogeneous catalysis through cooperative hybrid organic-inorganic interfaces

被引：212

作者：

Notestein, Justin M. ^{[1
]}

Katz, Alexander ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem Engn, Berkeley, CA 94720 USA

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2006年 / 12卷 / 15期

关键词：

cooperativity; enantioselectivity; heterogeneous catalysis; organic-inorganic hybrid composites; surface chemistry;

D O I：

10.1002/chem.200501152

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Active-site/surface cooperativity can enhance heterogeneous organic and organometallic catalysis. We review the powerful role of the solid surface in this context for generating local acidity and, as an inner-sphere ligand, for stabilizing immobilized supramolecular assemblies and unsaturated organometallic complexes that are often unstable in solution.

引用

页码：3954 / 3965

页数：12

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