Mechanical properties of plasma deposited polymer coatings

被引:42
作者
Benítez, F
Martínez, E
Galán, M
Serrat, J
Esteve, J
机构
[1] Univ Barcelona, Dept Fis Aplicada & Opt, E-08028 Barcelona, Spain
[2] TELSTAR SA, E-08226 Terrassa, Catalunya, Spain
关键词
adhesion; hardness; plasma polymerisation; surface modification;
D O I
10.1016/S0257-8972(99)00581-2
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Thin polymeric films have been obtained by plasma polymerisation of dimethylsiloxane (DMSO). Such films are widely used as protective coatings on optical reflective surfaces and decorative parts. Thin films of polydimethylsiloxane (PDMS) have been deposited by a DC glow discharge plasma from DMSO vapour on pre-treated and untreated polycarbonate (PC) substrates, with or without previous evaporation of an additional aluminium film. A subsequent process of mineralisation by immersion in an air plasma has been applied in order to improve the PDMS films wear resistance. Polycarbonate substrates have been treated in a similar way aiming at improved adhesion of Al films. The present paper is specially focused on the surface mechanical properties of these films. These have been measured by nanoindentation and microscratch techniques and the improvement of the surface hardness and scratch resistance of PDMS films and PC substrates has been assessed. (C) 2000 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:383 / 387
页数:5
相关论文
共 12 条
[1]  
Agres L, 1996, J APPL POLYM SCI, V61, P2015, DOI 10.1002/(SICI)1097-4628(19960912)61:11<2015::AID-APP16>3.0.CO
[2]  
2-7
[3]   Formation of hydrophobic layers on biologically degradable polymeric foils by plasma polymerization [J].
Behnisch, J ;
Tyczkowski, J ;
Gazicki, M ;
Pela, I ;
Hollander, A ;
Ledzion, R .
SURFACE & COATINGS TECHNOLOGY, 1998, 98 (1-3) :872-874
[4]   State-of-the-art overview: ion beam surface modification of polymers towards improving tribological properties [J].
Dong, H ;
Bell, T .
SURFACE & COATINGS TECHNOLOGY, 1999, 111 (01) :29-40
[5]   Plasma treatments and plasma deposition of polymers for biomedical applications [J].
Favia, P ;
d'Agostino, R .
SURFACE & COATINGS TECHNOLOGY, 1998, 98 (1-3) :1102-1106
[6]   Better aluminium mirrors by integrating plasma pretreatment, sputtering, and plasma polymerization for large-scale car headlight production [J].
Grünwald, H ;
Adam, R ;
Bartella, J ;
Jung, M ;
Dicken, W ;
Kunkel, S ;
Nauenburg, K ;
Gebele, T ;
Mitzlaff, S ;
Ickes, G ;
Patz, U ;
Snyder, J .
SURFACE & COATINGS TECHNOLOGY, 1999, 111 (2-3) :287-296
[7]  
HANSEN RH, 1966, J POLYM SCI, V4, P209
[8]   HARDNESS MEASUREMENTS OF AR+-BEAM TREATED POLYIMIDE BY DEPTH-SENSING ULTRA-LOW LOAD INDENTATION [J].
LEE, EH ;
LEE, Y ;
OLIVER, WC ;
MANSUR, LK .
JOURNAL OF MATERIALS RESEARCH, 1993, 8 (02) :377-387
[9]   AN IMPROVED TECHNIQUE FOR DETERMINING HARDNESS AND ELASTIC-MODULUS USING LOAD AND DISPLACEMENT SENSING INDENTATION EXPERIMENTS [J].
OLIVER, WC ;
PHARR, GM .
JOURNAL OF MATERIALS RESEARCH, 1992, 7 (06) :1564-1583
[10]   Aluminium metallisation of argon and oxygen plasma-modified polycarbonate thin film surfaces [J].
Rastomjee, CS ;
Keil, M ;
Sotobayashi, H ;
Bradshaw, AM ;
Lamont, CLA ;
Gador, D ;
Umbach, E .
APPLIED SURFACE SCIENCE, 1998, 136 (04) :280-297