Microwave irradiation in organophosphorus chemistry. Part 2: Synthesis of phosphonium salts

被引：53

作者：

Kiddle, JJ ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, Wilmington, NC 28403 USA

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 09期

关键词：

microwave heating; phosphonium salts; Wittig reaction; ylide;

D O I：

10.1016/S0040-4039(99)02288-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Several phosphonium salts have been prepared using a domestic microwave oven. The microwave enhanced reaction of triphenylphosphine and an organic halide shows a remarkable rate acceleration under microwave irradiation and allows the general and facile synthesis of both stabilized and non-stabilized phosphonium salts. (C) 2000 Elsevier Science Ltd. All. rights reserved.

引用

页码：1339 / 1341

页数：3

共 13 条

[1] MAGNETIC-RESONANCE STUDIES .2. INVESTIGATION OF PHOSPHONIUM SALTS CONTAINING UNSATURATED GROUPS BY C-13 AND P-13 NUCLEAR MAGNETIC-RESONANCE [J].