Molecular dynamics of organometallic compounds using mu SR

被引：17

作者：

Jayasooriya, UA ^{[1
]}

Aston, GM ^{[1
]}

Stride, JA ^{[1
]}

机构：

[1] HAHN MEITNER INST BERLIN GMBH,D-1000 BERLIN,GERMANY

来源：

APPLIED MAGNETIC RESONANCE | 1997年 / 13卷 / 1-2期

关键词：

D O I：

10.1007/BF03161978

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The potential of mu SR in the investigation of molecular dynamics of organometallic compounds is illustrated with applications to the classic metallocene compound, ferrocene. Muonium addition gives two radicals in this case with the slowly relaxing radical showing a repolarisation curve corresponding to a hyperfine field of ca. 200 G suggesting addition to the cyclopentadienyl ring. The temperature dependence of the relaxation of this radical gives an activation energy of ca. 5.4 kJ/mol, in good agreement with QENS and NMR estimates for cyclopentadienyl ring rotation in this compound.

引用

页码：165 / 171

页数：7

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