Antiferromagnetic interaction achieved by a 3-D supramolecular CuII complex with pyrazino-fused TTF as the ligand, [CuCl2(BP-TTF)]

被引：42

作者：

Ichikawa, Shun ^{[1
]}

Kimura, Shinya ^{[1
]}

Mori, Hatsumi ^{[1
]}

Yoshida, Gosuke ^{[1
]}

Tajima, Hiroyuki ^{[1
]}

机构：

[1] Univ Tokyo, Inst Solid State Phys, Kashiwa, Chiba 2778581, Japan

来源：

INORGANIC CHEMISTRY | 2006年 / 45卷 / 19期

关键词：

D O I：

10.1021/ic060746j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The diffusion reaction of TBA(2)Cu(II)Cl(4) (TBA = tetrabutylammonium) and a N-containing organic donor, BP-TTF [=bis(pyrazino)-tetrathiafulvalene], yielded a 3-D supramolecular Cu complex, [CuCl2(BP-TTF)] (1). The magnetic measurement of 1 exhibits an antiferromagnetic interaction by fitting a Bonner-Fisher model from 2 to 300 K with S = (1)/(2) and J = -3.5 K between Cu-II mediated by self-assembling donor columns.

引用

页码：7575 / 7577

页数：3

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