[Au2TI2(C6CI5)4]•(CH3)2C=O:: A luminescent loosely bound butterfly cluster with a TI(I)-TI(I) interaction

被引：62

作者：

Fernández, EJ

López-de-Luzuriaga, JM

Monge, M

Olmos, ME

Pérez, J

Laguna, A ^{[1
]}

机构：

[1] Univ Zaragoza, CSIC, ICMA, Dept Quim Inorgan, E-50009 Zaragoza, Spain

[2] Univ La Rioja, Dept Quim, Grp Sintesis Quim La Rioja, UA CSIC, E-26004 Logrono, Spain

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 21期

关键词：

D O I：

10.1021/ja017240e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By reaction of NBu4[Au(C6Cl5)2] with TlPF6 in acetone the complex [Au2Tl2(C6Cl5)4]·(CH3)2C=O is obtained, which shows a butterfly type arrangement of metals through short Au(I)-Tl(I) and Tl(I)-Tl(I) interactions. The last one is likely to be responsible for its luminescence behavior. Copyright © 2002 American Chemical Society.

引用

页码：5942 / 5943

页数：2

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