Two mixed-valence copper(I,II) imidazolate coordination polymers: metal-valence tuning approach for new topological structures

被引:144
作者
Huang, XC
Zhang, JP
Lin, YY
Yu, XL
Chen, XM [1 ]
机构
[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China
[2] Shantou Univ, Dept Chem, Shantou 515063, Guangdong, Peoples R China
关键词
D O I
10.1039/b401691b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new metal-valence tuning synthetic approach has been utilized to generate two new mixed-valence Cu(I,II) coordination polymers Cu-2(im)(3) and Cu-3(im)(4) (Him = imidazole), which are an unprecedented uninodal 4-connected 4.8(5) topological net and a 4-connected (4,4) net, respectively.
引用
收藏
页码:1100 / 1101
页数:2
相关论文
共 31 条
[1]  
Abrahams BF, 1999, ANGEW CHEM INT EDIT, V38, P1475, DOI 10.1002/(SICI)1521-3773(19990517)38:10<1475::AID-ANIE1475>3.0.CO
[2]  
2-3
[3]   X-H---π (X = O, N, C) Hydrogen bonds in organometallic crystals [J].
Braga, D ;
Grepioni, F ;
Tedesco, E .
ORGANOMETALLICS, 1998, 17 (12) :2669-2672
[4]   New examples of self-catenation in two three-dimensional polymeric co-ordination networks [J].
Carlucci, L ;
Ciani, G ;
Proserpio, DM ;
Rizzato, S .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (21) :3821-3827
[5]   Polycatenation, polythreading and polyknotting in coordination network chemistry [J].
Carlucci, L ;
Ciani, G ;
Proserpio, DM .
COORDINATION CHEMISTRY REVIEWS, 2003, 246 (1-2) :247-289
[6]   Open network architectures from the self-assembly of AgNO3 and 5,10,15,20-tetra(4pyridyl)porphyrin (H2tpyp) building blocks:: The exceptional self-penetrating topology of the 3D network of [Ag8(ZnIItpyp)7(H2O)2](NO3)8 [J].
Carlucci, L ;
Ciani, G ;
Proserpio, DM ;
Porta, F .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (03) :317-+
[7]   Blue-shifting hydrogen bonds [J].
Hobza, P ;
Havlas, Z .
CHEMICAL REVIEWS, 2000, 100 (11) :4253-4264
[8]  
HOLLEMAN AF, 1995, INORG CHEM, P610
[9]   Engineering coordination polymers towards applications [J].
Janiak, C .
DALTON TRANSACTIONS, 2003, (14) :2781-2804
[10]  
JARVIS JAJ, 1960, ACTA CRYSTALLOGR, V13, P1027