Kinetics of oxygen reduction at oxide-derived Pd electrodes in alkaline solution

被引:57
作者
Chang, CC
Wen, TC
Tien, HJ
机构
[1] NATL CHENG KUNG UNIV,DEPT CHEM ENGN,TAINAN 70101,TAIWAN
[2] NATL CHENG KUNG UNIV,DEPT CHEM,TAINAN 70101,TAIWAN
关键词
rotating disc electrode; oxide-derived Pd electrode; oxygen reduction;
D O I
10.1016/S0013-4686(96)00195-8
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Oxygen reduction at oxide-derived Pd electrodes is investigated by using the rotating disc electrode technique. On the basis of these experiments along with further data analysis (ie reaction orders, Tafel slopes, etc.), a mechanism of oxygen reduction on an oxide-derived Pd electrode is proposed to explain the observed rate equation. Copyright (C) 1996 Elsevier Science Ltd
引用
收藏
页码:557 / 565
页数:9
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