Photoinitiated Atom Transfer Radical Polymerization: Current Status and Future Perspectives

被引：143

作者：

Dadashi-Silab, Sajjad ^{[1
]}

Tasdelen, Mehmet Atilla ^{[2
]}

Yagci, Yusuf ^{[1
,3
,4
]}

机构：

[1] Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey

[2] Yalova Univ, Dept Polymer Engn, Fac Engn, TR-77100 Yalova, Turkey

[3] King Abdulaziz Univ, Ctr Excellence Adv Mat Res CEAMR, Fac Sci, Jeddah 21589, Saudi Arabia

[4] King Abdulaziz Univ, Dept Chem, Fac Sci, Jeddah 21589, Saudi Arabia

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2014年 / 52卷 / 20期

关键词：

atom transfer radical polymerization (ATRP); metal-organic catalysts/organometallic catalysts; photochemistry; photopolymerization; radical polymerization; GRAPHITIC CARBON NITRIDE; NORMAL INITIATION PROCESS; VISIBLE-LIGHT; ELECTRON-TRANSFER; METHYL-METHACRYLATE; SIMULTANEOUS REVERSE; BLOCK-COPOLYMERS; REDUCING AGENT; VINYL-CHLORIDE; ARGET ATRP;

D O I：

10.1002/pola.27327

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

In macromolecular and material science, atom transfer radical polymerization (ATRP) has intensely influenced the research strategies facilitating fabrication of a wide range of polymers with well-defined structures and functions and their conjugation with biomolecules. Recently, the required copper (I) catalyst for ATRP process is generated by photoinduced redox reactions involving the in situ reduction of Cu(II) to Cu(I). Photochemically initiated reactions provide several distinct advantages, including temporal and spatial controls, rapid and energy efficient activation. The process is based on photoredox reactions of copper catalysts under various radiation sources with or without various photoinitiators. This Highlight focuses on the historical development, mechanistic aspects, limitations, and opportunities of photoinitiated ATRP along with selected examples. (C) 2014 Wiley Periodicals, Inc.

引用

页码：2878 / 2888

页数：11

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