Synthesis of homophthalates from allenic diesters: Conversion into viocristin and analogues, and application to 6-methylpretetramid

被引：7

作者：

Caliskan, E ^{[1
]}

Cameron, DW ^{[1
]}

Griffiths, PG ^{[1
]}

机构：

[1] Univ Melbourne, Sch Chem, Parkville, Vic 3052, Australia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1999年 / 52卷 / 11期

基金：

澳大利亚研究理事会;

关键词：

D O I：

10.1071/CH99065

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oxy-substituted homophthalic anhydrides have been synthesized by cycloaddition of di- and tri-oxy butadienes to the allenic diester (1). By base-catalysed cycloaddition to appropriate benzoquinones they have afforded new syntheses of viocristin (19), isoviocristin (20) and analogous 1,4-anthraquinones. Related chemistry has led to the naphthalene (34) and the anhydride (35), intermediates in published syntheses of semivioxanthin and 6-methylpretetramid respectively.

引用

页码：1013 / 1020

页数：8

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