Phase coexistence in random copolymers

被引:18
作者
Dobrynin, AV
机构
[1] Department of Chemistry, University of North Carolina, Chapel Hill
关键词
D O I
10.1063/1.475215
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We study the phase coexistence in random copolymer systems. In the framework of the one-loop approximation it is shown that the phase transition between liquidlike and lamellar phases in the symmetric random copolymers occurs through the two-phase region. We derive an analytic expression describing the volume fi-actions of the coexisting phases in this region, To illustrate the phase behavior of the random copolymers, the phase diagram of a polydisperse A-B multiblock copolymer melt is calculated. (C) 1997 American Institute of Physics.
引用
收藏
页码:9234 / 9238
页数:5
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