Efficient charge separation in C60-based dyads:: Triazolino[4′,5′:1,2][60]fullerenes

被引：105

作者：

Guldi, DM ^{[1
]}

González, S

Martín, N

Antón, A

Garín, J

Orduna, J

机构：

[1] Univ Notre Dame, Radiat Lab, Notre Dame, IN 46556 USA

[2] Univ Complutense, Fac Ciencias Quim, Dept Quim Organ, E-28040 Madrid, Spain

[3] Univ Zaragoza, CSIC, ICMA, Dept Quim Organ, E-50009 Zaragoza, Spain

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2000年 / 65卷 / 07期

关键词：

D O I：

10.1021/jo991248d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Triazoline[4,5][60]fullerenes are strong electron accepters that form with tetrathiafulvalene (TTF), a novel type of donor-acceptor dyad exhibiting efficient improved electron-transfer dynamics. In particular, a rapid photoinduced intramolecular electron transfer, forming a charge-separated state, is followed by a slow charge recombination to generate the fullerene triplet excited state in moderate quantum yields.

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页码：1978 / 1983

页数：6

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