Microwave-assisted synthesis of N,N-bis-(2-pyridylmethyl)amine derivatives.: Useful ligands in coordination chemistry

被引：14

作者：

Pimentel, Luiz Claudio F. ^{[1
]}

de Souza, Andrea Luzia F. ^{[1
]}

Fernandez, Tatiana Lopez ^{[1
]}

Wardell, James L. ^{[1
]}

Antunes, O. A. C. ^{[1
]}

机构：

[1] Univ Fed Rio de Janeiro, Inst Quim, BR-21945970 Rio De Janeiro, RJ, Brazil

来源：

TETRAHEDRON LETTERS | 2007年 / 48卷 / 05期

关键词：

D O I：

10.1016/j.tetlet.2006.11.154

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Microwave-assisted synthesis of the ligands N,N-bis-(2-pyridylmethyl)amine (BMPA), N-(methylpropanoate)-N,N-bis(2-pyridylmethyl)amine (MPBMPA), N-(propanamide)-N,N-bis-(2-pyridylmethyl)amine (PABMPA), PNBMPA (N-(3-propio-nitrile)-N,N-bis-(2-pyridylmethyl)amine), N-(3-aminopropyl)-N,N-bis-(2-pyridylmethyl)amine (APBMPA), and lithium N-(propono-ate) -N, N-bis-(2-pyridylmethyl) amine (LiPBMPA) are reported. High yields and short reaction time were obtained for condensation and Michael addition. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：831 / 833

页数：3

共 36 条

[1] Production of piperonal, vanillin, and p-anisaldehyde via solventless supported iodobenzene diacetate oxidation of isosafrol, isoeugenol, and anethol under microwave irradiation [J].

Alvarez, Heiddy Marquez ;

Barbosa, Dayse P. ;

Fricks, Alini Tinoco ;

Aranda, Donato A. G. ;

Valdes, Ricardo H. ;

Antunes, O. A. C. .

ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2006, 10 (05) :941-943

[2] Synthesis of new Cu(II)-chelating ligand amphiphiles and their esterolytic properties in cationic micelles [J].

Bhattacharya, S ;

Snehalatha, K ;

Kumar, VP .

JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (07) :2741-2747

[3] Synthesis of some copper(II)-chelating (dialkylamino)pyridine amphiphiles and evaluation of their esterolytic capacities in cationic micellar media [J].

Bhattacharya, S ;

Snehalatha, K ;

George, SK .

JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (01) :27-35

[4] MICROWAVE-ASSISTED ORGANIC-REACTIONS [J].

CADDICK, S .

TETRAHEDRON, 1995, 51 (38) :10403-10432

[5] Metal complexes: from pioneers to the GTC [J].

Carunchio, V .

POLYHEDRON, 2002, 21 (14-15) :1313-1318

[6] Synthesis, characterization, X-ray molecular structure and catalase-like activity of a non-heme iron complex:: Dichloro[N-propanoate-N,N-bis-(2-pyridylmethyl)amine]iron(III) [J].

Carvalho, Nakedia M. F. ;

Horn, Adolfo, Jr. ;

Faria, Roberto B. ;

Bortoluzzi, Adailton J. ;

Drago, Valderes ;

Antunes, O. A. C. .

INORGANICA CHIMICA ACTA, 2006, 359 (13) :4250-4258

[7] Cyclohexane oxidation catalyzed by mononuclear iron(III) complexes [J].

Carvalho, Nakedia M. F. ;

Horn, Adolfo, Jr. ;

Antunes, O. A. C. .

APPLIED CATALYSIS A-GENERAL, 2006, 305 (02) :140-145

[8] Synthesis and characterization of three mononuclear Fe(III) complexes containing bipodal and tripodal ligands:: X-ray molecular structure of the dichloro[N-propanamide-N,N-bis-(2-pyridylmethyl)amine]iron(III) perchlorate [J].

Carvalho, NMF ;

Horn, A ;

Bortoluzzi, AJ ;

Drago, V ;

Antunes, OAC .

INORGANICA CHIMICA ACTA, 2006, 359 (01) :90-98

[9]

de la Hoz A, 2000, EUR J ORG CHEM, V2000, P3659

[10] Reactions of [{bis(2-pyridylmethyl)amine}trichloroiron(III)] with (HOCH2)3CNHCO(CH2)nCONHC(CH2OH)3 (n=0-2):: crystal structures of (μ-oxo)bis{(oxalato){[bis(pyridylmethyl)amine]iron(III)} and (HOCH2)3CNHCO(CH2)2CONHC(CH2OH)3 [J].

Fernandes, C ;

Wardell, JL ;

Horn, A ;

Skakle, JMS ;

Drago, V .

POLYHEDRON, 2004, 23 (08) :1419-1426

← 1 2 3 4 →