Polymer-bound 1-aryl-3-alkyltriazenes as modular ligands for catalysis.: Part 2:: Screening immobilized metal complexes for catalytic activity

被引:22
作者
Bräse, S
Dahmen, S
Lauterwasser, F
Leadbeater, NE
Sharp, EL
机构
[1] Univ Bonn, Kekule Inst Organ Chem & Biochem, D-53121 Bonn, Germany
[2] Rhein Westfal TH Aachen, Inst Organ Chem, D-52074 Aachen, Germany
[3] Kings Coll London, Dept Chem, London WC2R 2LS, England
关键词
D O I
10.1016/S0960-894X(02)00279-2
中图分类号
R914 [药物化学];
学科分类号
100701 ;
摘要
A range of polymer-supported triazenes and their metal-bound analogues were screened for use in catalysis. Fe, Cu and Zr complexes were, together with the polymer-supported triazene ligand alone, screened in the addition of Et2Zn to benzaldehyde. A supported Pd triazene complex was screened for activity, in Suzuki and Sonogashira reactions and a supported Ru triazene complex screened for transfer hydrogenation. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1849 / 1851
页数:3
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