High-field, multifrequency EPR study of the vanadium(III) hexaaqua cation

被引：69

作者：

Tregenna-Piggott, PLW

Weihe, H

Bendix, J

Barra, AL

Güdel, HU

机构：

[1] Univ Bern, Dept Chem, CH-3000 Bern 9, Switzerland

[2] Inst Chem, DK-2100 Copenhagen, Denmark

[3] CNRS, Grenoble High Magnet Field Lab, LCMI, F-38042 Grenoble 9, France

来源：

INORGANIC CHEMISTRY | 1999年 / 38卷 / 26期

关键词：

D O I：

10.1021/ic990399w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

High-field, multifrequency EPR data are presented for vanadium(III)-doped CsGa(SO4)(2).12X(2)O, where X = D or H, which afford the direct determination of the spin-Hamiltonian parameters pertaining to the (3)A(g) (S-6) ground term. A pronounced change in the g values and zero-field splitting is observed upon isotopic substitution which cannot be simply explained using a conventional ligand field model.

引用

页码：5928 / +

页数：3

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