X-ray scattering study of CSA protonated polyaniline films and powders

被引：27

作者：

Djurado, D

Nicolau, YF

Dalsegg, I

Samuelsen, EJ

机构：

[1] CEN GRENOBLE,CEA,DEPT RECH FONDAMENTALE MAT CONDENSEE,S13M,PMS,F-38054 GRENOBLE 9,FRANCE

[2] UNIV TRONDHEIM,NTH,DEPT PHYS,N-7034 TRONDHEIM,NORWAY

来源：

SYNTHETIC METALS | 1997年 / 84卷 / 1-3期

关键词：

X-ray diffraction; polycrystalline thin films; polyaniline and derivatives;

D O I：

10.1016/S0379-6779(97)80675-3

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

An X-ray scattering study was carried out on camphorsulfonic acid-protonated emeraldine base samples in water, m-cresol and in their mixtures. The X-ray profiles strongly depend on the protonation conditions and on the molecular weight of the emeraldine base (EB). The protonation of the EB in solution in m-cresol enables a better crystallization than inside the EB powder suspended in aqueous acidic solution. X-ray profiles evolved when protonated EB m-cresol-free samples were exposed to m-cresol vapors, indicating that m-cresol enhances the crystallinity and the structural order. All different X-ray profiles of the films could be indexed with a sole orthorhombic cell with a = 21.5 Angstrom, b = (2x) 3.5 Angstrom and c = 18.6 Angstrom.

引用

页码：121 / 122

页数：2

共 5 条

[1] ON THE MOLECULAR RECOGNITION AND ASSOCIATIONS BETWEEN ELECTRICALLY CONDUCTING POLYANILINE AND SOLVENTS [J].