Crystal structure of the molecular adduct of 5-mono[(4-nitrophenyl)azo]-25,26,27,28-tetrahydroxycalix[4]arene with chloroform (1:1)

被引：3

作者：

Jin, CM ^{[1
]}

Wang, Z ^{[1
]}

Zhang, KL ^{[1
]}

Lu, GY ^{[1
]}

You, XZ ^{[1
]}

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Dept Chem, Nanjing 210093, Peoples R China

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2002年 / 32卷 / 09期

关键词：

azocalix[4]arene; molecular adduct; chloroform; crystal structure;

D O I：

10.1023/A:1020253423983

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal structure of the molecular adduct of 5-mono[(4-nitrophenyl)azo]-25,26,27,28-tetrahydroxycalix[4]arene (2) with chloroform (C(3)4H(2)7N(3)O(6) . CHCl3) was determined by X-ray crystallographic analysis. It was found to possess a monoclinic space group P2(1)/n, with a = 15.9306(13) Angstrom, b = 10.6293(9) Angstrom, c = 20.3194(17) Angstrom, beta = 110.480(2)degrees and D-calc = 1.428 Mg/m(3) for (Z) = 4. Crystal data indicated that the calix[4]arene moiety of 2 exists in a distorted-cone conformation with intramolecular hydrogen bonds.

引用

页码：293 / 297

页数：5

共 20 条

[1] DISSYMMETRIC CALIX[4]ARENES WITH C4-SYMMETRY AND C2-SYMMETRY - SYNTHESIS, X-RAY STRUCTURES, CONFORMATIONAL FIXATION, AND H-1-NMR SPECTROSCOPIC STUDIES [J].

ANDREETTI, GD ;

BOHMER, V ;

JORDON, JG ;

TABATABAI, M ;

UGOZZOLI, F ;

VOGT, W ;

WOLFF, A .

JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (15) :4023-4032

[2]

ANTREETTI GD, 1979, J CHEM SOC CHEM COMM, P1006

[3]

*BRUK AXS INC, 1997, SMART SAINT SHELXTL

[4]

GREEN RD, 1974, HYDROGEN BONDING C D

[5] ARENE ARENE INTERACTIONS - ELECTROSTATIC OR CHARGE-TRANSFER [J].

HUNTER, CA .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (11) :1584-1586

[6] Novel cavity design using calix[n]arene skeletons: Toward molecular recognition and metal binding [J].

Ikeda, A ;

Shinkai, S .

CHEMICAL REVIEWS, 1997, 97 (05) :1713-1734

[7] C-13 NMR CHEMICAL-SHIFTS - A SINGLE RULE TO DETERMINE THE CONFORMATION OF CALIX[4]ARENES [J].

JAIME, C ;

DEMENDOZA, J ;

PRADOS, P ;

NIETO, PM ;

SANCHEZ, C .

JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (10) :3372-3376

[8]

Lu GY, 2000, CHINESE J CHEM, V18, P207

[9] SYNTHESES AND NMR BEHAVIOR OF CALIX[4]QUINONE AND CALIX[4]HYDROQUINONE [J].

MORITA, Y ;

AGAWA, T ;

NOMURA, E ;

TANIGUCHI, H .

JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (13) :3658-3662

[10] SELECTIVE ION EXTRACTION BY A CALIX[6]ARENE DERIVATIVE CONTAINING AZO GROUPS [J].

NOMURA, E ;

TANIGUCHI, H ;

TAMURA, S .

CHEMISTRY LETTERS, 1989, (07) :1125-1126

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