Long-range self-assembly of a polyunsaturated linear organosilane at the n-Tetradecane/Au(111) interface studied by STM

被引：51

作者：

Marchenko, A

Katsonis, N

Fichou, D ^{[1
]}

Aubert, C

Malacria, M

机构：

[1] CEA Saclay, Serv Phys & Chim Surfaces & Interfaces, DRECAM, DSM, F-91191 Gif Sur Yvette, France

[2] Univ Paris 06, CNRS, UMR 7611, Chim Organ Lab, F-75252 Paris, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 34期

关键词：

D O I：

10.1021/ja027002z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report on the formation of self-assembled monolayers of 13-(trimethylsilyl)-1-tridecene-6,12-diyne [C13H17-Si(CH3)3], an organosilane derivative with a linear polyunsaturated chain, on Au(111) substrates. Molecular resolution STM images recorded at the liquid-solid interface between gold and tetradecane reveal a long-range and densely packed hexagonal lattice with a (√3 × √3)R30°-like structure commensurate against gold adlattice. Copyright © 2002 American Chemical Society.

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页码：9998 / 9999

页数：2

相关论文

共 27 条

[1] INTERACTIONS BETWEEN ORGANIZED, SURFACE-CONFINED MONOLAYERS AND VAPOR-PHASE PROBE MOLECULES .7. COMPARISON OF SELF-ASSEMBLING N-ALKANETHIOL MONOLAYERS DEPOSITED ON GOLD FROM LIQUID AND VAPOR-PHASES [J].

CHAILAPAKUL, O ;

SUN, L ;

XU, CJ ;

CROOKS, RM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (26) :12459-12467

[2] REACTIVITY OF PENTACOORDINATE AND HEXACOORDINATE SILICON-COMPOUNDS AND THEIR ROLE AS REACTION INTERMEDIATES [J].

CHUIT, C ;

CORRIU, RJP ;

REYE, C ;

YOUNG, JC .

CHEMICAL REVIEWS, 1993, 93 (04) :1371-1448

[3] Low-voltage, 30 nm channel length, organic transistors with a self-assembled monolayer as gate insulating films [J].

Collet, J ;

Tharaud, O ;

Chapoton, A ;

Vuillaume, D .

APPLIED PHYSICS LETTERS, 2000, 76 (14) :1941-1943

[4] THERMAL-STABILITY OF SELF-ASSEMBLED MONOLAYERS [J].

DELAMARCHE, E ;

MICHEL, B ;

KANG, H ;

GERBER, C .

LANGMUIR, 1994, 10 (11) :4103-4108

[5] CHEMISTRY OF ENOXYSILACYCLOBUTANES - HIGHLY SELECTIVE UNCATALYZED ALDOL ADDITIONS [J].

DENMARK, SE ;

GRIEDEL, BD ;

COE, DM ;

SCHNUTE, ME .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (16) :7026-7043

[6] Self-assembly of conjugated molecular rods: A high-resolution STM study [J].

Dhirani, AA ;

Zehner, RW ;

Hsung, RP ;

GuyotSionnest, P ;

Sita, LR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (13) :3319-3320

[7] ELECTRONIC AND MECHANICAL CHARACTERIZATION OF SELF-ASSEMBLED ALKANETHIOL MONOLAYERS BY SCANNING-TUNNELING-MICROSCOPY COMBINED WITH INTERACTION-FORCE-GRADIENT SENSING [J].

DURIG, U ;

ZUGER, O ;

MICHEL, B ;

HAUSSLING, L ;

RINGSDORF, H .

PHYSICAL REVIEW B, 1993, 48 (03) :1711-1717

[8] FORMATION OF SELF-ASSEMBLED MONOLAYERS OF N-ALKANETHIOLS ON GOLD - A SCANNING TUNNELING MICROSCOPY STUDY ON THE MODIFICATION OF SUBSTRATE MORPHOLOGY [J].

EDINGER, K ;

GOLZHAUSER, A ;

DEMOTA, K ;

WOLL, C ;

GRUNZE, M .

LANGMUIR, 1993, 9 (01) :4-8

[9] Formation and patterning of self-assembled monolayers derived from long-chain organosilicon amphiphiles and their use as templates in materials microfabrication [J].

Finnie, KR ;

Haasch, R ;

Nuzzo, RG .

LANGMUIR, 2000, 16 (17) :6968-6976

[10]

Hooks DE, 2001, ADV MATER, V13, P227, DOI 10.1002/1521-4095(200102)13:4<227::AID-ADMA227>3.0.CO