Impedance of boundaries bi-ionic oxide vanadium bronzes/Na+-conducting solid electrolytes

被引：1

作者：

Bukun, NG ^{[1
]}

Nadkhina, SE

Leonova, LS

Levchenko, AV

Kolesnikova, AM

Osadchii, EG

机构：

[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Russia

[2] Russian Acad Sci, Inst Expt Mineral, Chernogolovka 142432, Russia

来源：

SOLID STATE IONICS | 2004年 / 169卷 / 1-4期

关键词：

oxide vanadium bronzes; zNa(0.3)3V(2)O(5)-(1-z)Ca(Sr)(0.165)V2O5 systems; electronic conductivity; ion exchange current;

D O I：

10.1016/j.ssi.2004.01.011

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Bi-ionic oxide bronzes of the A(x)BO(y) type (A = Na, Ca, Na-Ca, Sr, Na-Sr; B = V) were synthesized by solid state method. The values of partial electronic conductivity in the zNa(0.33)V(2)O(5)-(1-z)Ca(Sr)(0.165)V2O5 systems and ionic reversibility at the zNa(0.33)V(2)O(5)-(1-z) Sr0.165V2O5/Na3Zr2Si2PO12 interface were determined as functions of Na0.33V2O5 content. It has been found that the ion substitution process Sr2+ double left right arrow 2Na(+) occurs at the Sr0.165V2O5/Na+-SE interface. (C) 2004 Elsevier B.V All rights reserved.

引用

页码：41 / 45

页数：5

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