Dismantling a dinuclear metallacyclopentadiene: Alkyne scission in cobalt-molybdenum clusters

被引：10

作者：

Adams, H ^{[1
]}

Gill, LJ ^{[1
]}

Morris, MJ ^{[1
]}

机构：

[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 20期

关键词：

D O I：

10.1039/dt9960003909

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The alkyne complexes [Mo-2(mu-C(2)Ph(2))(CO)(4)(eta-C5H5)(2)] and [Co-2(mu-C(2)Ph(2))(CO)(6)] reacted together to give the butterfly cluster [Co2Mo2(mu(3)-CPh)(2)(mu(4)-C(2)Ph(2))(CO)(4)(eta-C5H5)(2)], which can also be made from [Mo-2(mu-C(4)Ph(4))(CO)(eta-C5H5)(2)] and [Co-2(CO)(8)]; the possible role of the C(4)Ph(4) complex as an intermediate in the former transformation is discussed.

引用

页码：3909 / 3910

页数：2

共 17 条

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