mer-triaqua(chloranilato-O,O')chloro-iron(III) pentahydrate

被引:10
作者
Abrahams, BF
Hoskins, BF
Robson, R
机构
[1] School of Chemistry, University of Melbourne, Parkville
关键词
D O I
10.1107/S010827019600577X
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The crystal structure of the title compound, [FeCl(C6Cl2O4)(H2O)(3)].5H(2)O, shows it to be a monomeric iron(III) complex with the metal ion chelated by the dianion of chloranilic acid (2,5-dichloro-3,6-dihydroxy-2,5-cyclohexadiene- 1,4-dione). The octahedral coordination environment is completed by a chloride ion and three water molecules which are in a mer arrangement. Extensive hydrogen bonding occurs between the complex and lattice water molecules.
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页码:2766 / 2768
页数:3
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