Asymmetric epoxidation of non-functionalized alkenes using transition metal complexes

被引：7

作者：

Abdi, SHR ^{[1
]}

Kureshy, RI ^{[1
]}

Khan, NH ^{[1
]}

Jasra, RV ^{[1
]}

机构：

[1] Cent Salt & Marine Chem Res Inst, Silicates & Catalysis Discipline, Bhavnagar 364002, Gujarat, India

来源：

CATALYSIS SURVEYS FROM ASIA | 2004年 / 8卷 / 03期

关键词：

asymmetric catalysis; chiral; non-functionalized alkenes; transition metals; salen; epoxide;

D O I：

10.1023/B:CATS.0000038537.27684.b4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Asymmetric catalytic epoxidation of alkenes such as styrenes, chromenes and indene using transition metal complexes both inhomogeneous and heterogeneous phase has been discussed in this review. The various strategies to make the catalysts recyclable by introducing in-built phase transfer ability, converting these to dimeric form, exchanging into clays and supporting on polymeric or inorganic supports are discussed at length.

引用

页码：187 / 197

页数：11

共 66 条

[1] Enantioselective epoxidation reaction of non-functionalised prochiral alkenes using optically resolved [brucine](R)-[Ru(PDTA-H)Cl] and [brucine](S)-[Ru(PDTA-H)Cl] complexes
Abdi, SHR
Kureshy, RI
Khan, NH
Bhadbhade, MM
Suresh, E
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 150 (1-2) : 185 - 194
[2] [Anonymous], CYTOCHROME P 450 MEC
[3] Heterogeneous enantioselective epoxidation of olefins catalysed by unsymmetrical (salen) Mn(III) complexes supported on amorphous or MCM-41 silica through a new triazine-based linker
Bigi, F
Moroni, L
Maggi, R
Sartori, G
[J]. CHEMICAL COMMUNICATIONS, 2002, (07) : 716 - 717
[4] Bolm C, 1997, SYNLETT, P687
[5] Utilisation of homogeneous and supported chiral metal(salen) complexes in asymmetric catalysis
Canali, L
Sherrington, DC
[J]. CHEMICAL SOCIETY REVIEWS, 1999, 28 (02) : 85 - 93
[6] Remarkable matrix effect in polymer-supported Jacobsen's alkene epoxidation catalysts
Canali, L
Cowan, E
Deleuze, H
Gibson, CL
Sherrington, DC
[J]. CHEMICAL COMMUNICATIONS, 1998, (23) : 2561 - 2562
[7] SHAPE-SELECTIVE OLEFIN EPOXIDATION CATALYZED BY MANGANESE PICNIC BASKET PORPHYRINS
COLLMAN, JP
ZHANG, XM
HEMBRE, RT
BRAUMAN, JI
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (13) : 5356 - 5357
[8] Crosby J., 1992, CHIRALITY IND, P1
[9] De BB, 1997, J POLYM SCI POL CHEM, V35, P1809
[10] DERANTER CJ, 1984, XRAY CRYSTALLOGRAPHY, P3

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