Simple model for attraction between like-charged polyions

被引:112
作者
Arenzon, JJ
Stilck, JF
Levin, Y
机构
[1] Univ Fed Rio Grande Sul, Inst Fis, BR-91501970 Porto Alegre, RS, Brazil
[2] Univ Fed Fluminense, Inst Fis, BR-24210340 Niteroi, RJ, Brazil
关键词
D O I
10.1007/s100510050980
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
We present a simple model for the possible mechanism of appearance of attraction between like charged polyions inside a polyelectrolyte solution. The attraction is found to be short ranged, and exists only in the presence of multivalent counterions. It is produced by the correlations in layers of condensed counterions surrounding each polyion and is only weakly temperature dependent. We find the attraction to be maximum at zero temperature and dimish as the temperature is raised. The attraction is only possible if the number of condensed counterions exceeds the threshold, n > Z/2 alpha, where a is the valence of counterions and Z is the polyion charge.
引用
收藏
页码:79 / 82
页数:4
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