Tunable Optical Gap at a Fixed Lattice Constant in Group-IV Semiconductor Alloys

被引:108
作者
D'Costa, V. R. [1 ]
Fang, Y. -Y. [2 ]
Tolle, J. [2 ]
Kouvetakis, J. [2 ]
Menendez, J. [1 ]
机构
[1] Arizona State Univ, Dept Phys, Tempe, AZ 85287 USA
[2] Arizona State Univ, Dept Chem & Biochem, Tempe, AZ 85287 USA
关键词
PARAMETERS;
D O I
10.1103/PhysRevLett.102.107403
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
A direct absorption edge tunable between 0.8 and similar to 1.4 eV is demonstrated in strain-free ternary Ge1-x-ySixSny alloys epitaxially grown on Ge-buffered Si. This decoupling of electronic structure and lattice parameter-unprecedented in group-IV alloys-opens up new possibilities in silicon photonics, particularly in the field of photovoltaics. The compositional dependence of the direct band gap in Ge1-x-ySixSny exhibits a nonmonotonic behavior that is explained in terms of coexisting small and giant bowing parameters in the two-dimensional compositional space.
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页数:4
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