Efficient extraction of quantum Hamiltonians from optimal laboratory data

被引:8
作者
Geremia, JM [1 ]
Rabitz, HA
机构
[1] CALTECH, Pasadena, CA 91125 USA
[2] Princeton Univ, Dept Chem, Princeton, NJ 08540 USA
来源
PHYSICAL REVIEW A | 2004年 / 70卷 / 02期
关键词
D O I
10.1103/PhysRevA.70.023804
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Optimal identification (OI) is a recently developed procedure for extracting information about quantum Hamiltonians from experimental data. It employs techniques from coherent learning control to drive the quantum system such that dynamical measurements provide maximal information about its Hamiltonian. OI is an optimal procedure as initially presented; however, the data inversion component is computationally expensive. Here, we demonstrate that highly efficient global, nonlinear, map-facilitated inversion procedures can be combined with the OI concept to make it more suitable for laboratory implementation. A simulation of map-facilitated OI illustrates how the input-output maps can greatly accelerate the data inversion process.
引用
收藏
页码:023804 / 1
页数:6
相关论文
共 17 条
[1]  
GEREMIA J, 2003, PHYS REV A, V67, P401
[2]   Optimal identification of Hamiltonian information by closed-loop laser control of quantum systems [J].
Geremia, JM ;
Rabitz, H .
PHYSICAL REVIEW LETTERS, 2002, 89 (26) :1-263902
[3]   Optimal Hamiltonian identification: The synthesis of quantum optimal control and quantum inversion [J].
Geremia, JM ;
Rabitz, H .
JOURNAL OF CHEMICAL PHYSICS, 2003, 118 (12) :5369-5382
[4]   Global, nonlinear algorithm for inverting quantum-mechanical observations [J].
Geremia, JM ;
Rabitz, H .
PHYSICAL REVIEW A, 2001, 64 (02) :13
[5]   The Ar-HCl potential energy surface from a global map-facilitated inversion of state-to-state rotationally resolved differential scattering cross sections and rovibrational spectral data [J].
Geremia, JM ;
Rabitz, H .
JOURNAL OF CHEMICAL PHYSICS, 2001, 115 (19) :8899-8912
[6]   Constructing global functional maps between molecular potentials and quantum observables [J].
Geremia, JM ;
Rabitz, H ;
Rosenthal, C .
JOURNAL OF CHEMICAL PHYSICS, 2001, 114 (21) :9325-9336
[7]   Achieving the laboratory control of quantum dynamics phenomena using nonlinear functional maps [J].
Geremia, JM ;
Weiss, E ;
Rabitz, H .
CHEMICAL PHYSICS, 2001, 267 (1-3) :209-222
[8]   DETERMINATION OF THE INTERATOMIC POTENTIAL FROM ELASTIC DIFFERENTIAL CROSS-SECTIONS AT FIXED ENERGY - FUNCTIONAL SENSITIVITY ANALYSIS APPROACH [J].
HO, T ;
RABITZ, H .
JOURNAL OF CHEMICAL PHYSICS, 1989, 90 (03) :1519-1525
[9]   TEACHING LASERS TO CONTROL MOLECULES [J].
JUDSON, RS ;
RABITZ, H .
PHYSICAL REVIEW LETTERS, 1992, 68 (10) :1500-1503
[10]  
Miller K., 1970, SIAM J. Math. Anal, V1, P52, DOI [10.1137/0501006, DOI 10.1137/0501006]