New bipyridyl ligands bearing azo- and imino-linked chromophores. Synthesis and nonlinear optical studies of related dipolar zinc complexes

被引:61
作者
Hilton, A
Renouard, T
Maury, O
Le Bozec, H
Ledoux, I
Zyss, J
机构
[1] Univ Rennes 1, Lab Chim Coordinat & Catalyse, CNRS, UMR 6509, F-35042 Rennes, France
[2] ENS Cachan, Lab Phys Quant Mol, F-94235 Cachan, France
关键词
D O I
10.1039/a908197f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis and optical properties of 4,4'-bis(dialkylaminophenylazo)-2,2'-bipyridine and 4,4'-bis(dialkylaminophenylimino)-2,2'-bipyridine ligands are described; the corresponding dipolar bipyridyl zinc dichloride complexes have been prepared and their second order nonlinear optical properties determined by electric field-induced second harmonic generation (EFISH) at 1.34 mu m.
引用
收藏
页码:2521 / 2522
页数:2
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