Recent Highlights and Perspectives on Acene Based Molecules and Materials

被引:262
作者
Ye, Qun [1 ]
Chi, Chunyan [1 ]
机构
[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore
关键词
THIN-FILM TRANSISTORS; POLYCYCLIC AROMATIC-HYDROCARBON; PALLADIUM-CATALYZED CYANATION; SINGLET EXCITON FISSION; PHYSICAL-PROPERTIES; GROUND-STATE; ELECTRONIC-STRUCTURE; CHARGE SEPARATION; CRYSTAL-STRUCTURE; CARBON NANOTUBES;
D O I
10.1021/cm501536p
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Acenes represent a series of molecules with intriguing physical and chemical properties for applications in organic electronics. Nevertheless, the stability and solubility issues associated with longer acenes are two major obstacles for their applications. In this Perspective, we summarize the major design principles for stabilizing acenes. A variety of stable acene based derivatives are included for discussion. Finally, we highlight some research areas where breakthroughs will be critical for the further development of acene based molecules and materials.
引用
收藏
页码:4046 / 4056
页数:11
相关论文
共 151 条
[1]   The larger acenes: Versatile organic semiconductors [J].
Anthony, John E. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (03) :452-483
[2]   Functionalized acenes and heteroacenes for organic electronics [J].
Anthony, John E. .
CHEMICAL REVIEWS, 2006, 106 (12) :5028-5048
[3]   TOWARDS THE MAKING OF [12]COLLARENE [J].
ASHTON, PR ;
ISAACS, NS ;
KOHNKE, FH ;
SLAWIN, AMZ ;
SPENCER, CM ;
STODDART, JF ;
WILLIAMS, DJ .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (07) :966-969
[4]   Dibenzopentarylenebis(dicarboximide)s:: Novel near-infrared absorbing dyes [J].
Avlasevich, Yuri ;
Muellen, Klaus .
CHEMICAL COMMUNICATIONS, 2006, (42) :4440-4442
[5]   Extended 7,7,8,8-Tetracyano-p-quinodimethane-Based Acceptors: How Molecular Shape and Packing Impact Electron Accepting Behavior [J].
Bader, Mamoun M. ;
Pham, Phuong-Truc T. ;
Nassar, Basant R. ;
Lin, Hui ;
Xia, Yu ;
Frisbie, C. Daniel .
CRYSTAL GROWTH & DESIGN, 2009, 9 (11) :4599-4601
[6]   CYCLIC DIENES .11. NEW SYNTHESES OF HEXACENE AND HEPTACENE [J].
BAILEY, WJ ;
LIAO, CW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1955, 77 (04) :992-993
[7]   Tetrathiafulvalenes, oligoacenenes, and their buckminsterfullerene derivatives: The brick and mortar of organic electronics [J].
Bendikov, M ;
Wudl, F ;
Perepichka, DF .
CHEMICAL REVIEWS, 2004, 104 (11) :4891-4945
[8]   Oligoacenes: Theoretical prediction of open-shell singlet diradical ground states [J].
Bendikov, M ;
Duong, HM ;
Starkey, K ;
Houk, KN ;
Carter, EA ;
Wudl, F .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (24) :7416-7417
[9]   Stable photoinduced charge separation in heptacene [J].
Bettinger, Holger F. ;
Mondal, Rajib ;
Neckers, Douglas C. .
CHEMICAL COMMUNICATIONS, 2007, (48) :5209-5211
[10]   Electronic structure of higher acenes and polyacene: The perspective developed by theoretical analyses [J].
Bettinger, Holger F. .
PURE AND APPLIED CHEMISTRY, 2010, 82 (04) :905-915