Geometry of excited states of transition metal complexes from resonance Raman data and quantum chemical calculations

被引：10

作者：

Baranovski, VI ^{[1
]}

Lubimova, OO ^{[1
]}

Makarov, AA ^{[1
]}

Sizova, OV ^{[1
]}

机构：

[1] St Petersburg State Univ, Fac Chem, St Petersburg 198504, Russia

来源：

CHEMICAL PHYSICS LETTERS | 2002年 / 361卷 / 3-4期

关键词：

D O I：

10.1016/S0009-2614(02)00977-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The method of estimation of the geometry changes due to electronic excitations using resonance Raman intensities and the results of quantum chemical calculations was extended on the transition metal complexes with organic ligands. The local nature of the MLCT transitions greatly simplifies the method in that it is possible to work only with a fragment of the initial rather complicated complex ion. The method is applied to the study of the Ru(II) complexes with 2,2'-bipyridine. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：196 / 202

页数：7

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