X-ray emission spectroscopy of hydrogen bonding and electronic structure of liquid water -: art. no. 137402

被引：217

作者：

Guo, JH

Luo, Y

Augustsson, A

Rubensson, JE

Såthe, C

Ågren, H

Siegbahn, H

Nordgren, J

机构：

[1] Uppsala Univ, Dept Phys, SE-75121 Uppsala, Sweden

[2] Royal Inst Technol, S-10044 Stockholm, Sweden

[3] Univ Calif Berkeley, Lawrence Berkeley Lab, Adv Light Source, Berkeley, CA 94720 USA

来源：

PHYSICAL REVIEW LETTERS | 2002年 / 89卷 / 13期

关键词：

D O I：

10.1103/PhysRevLett.89.137402

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

We use x-ray emission spectroscopy to examine the influence of the intermolecular interaction on the local electronic structure of liquid water. By comparing x-ray emission spectra of the water molecule and liquid water, we find a strong involvement of the a(1)-symmetry valence-orbital in the hydrogen bonding. The local electronic structure of water molecules, where one hydrogen bond is broken at the hydrogen site, is separately determined. Our results provide an illustration of the important potential of x-ray emission spectroscopy for elucidating basic features of liquids.

引用

页码：137402 / 137402

页数：4

共 35 条

[1] [Anonymous], PHYS REV B
[2] ELECTRONIC-STRUCTURE OF BI2SR2CACU2O8+DELTA AND TL2BA2CACU2O8 - NEAR-O-1S-THRESHOLD EXCITATION X-RAY FLUORESENCE STUDIES
BUTORIN, SM
GUO, JH
WASSDAHL, N
SKYTT, P
NORDGREN, J
MA, Y
STROM, C
JOHANSSON, LG
QVARFORD, M
[J]. PHYSICAL REVIEW B, 1995, 51 (17): : 11915 - 11923
[3] ELECTRONIC-STRUCTURE OF THE VALENCE BANDS OF SOLID NH3 AND H2O STUDIED BY ULTRAVIOLET PHOTOELECTRON-SPECTROSCOPY
CAMPBELL, MJ
LIESEGANG, J
RILEY, JD
LECKEY, RCG
JENKIN, JG
POOLE, RT
[J]. JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1979, 15 (JAN) : 83 - 90
[4] VIBRONIC EMISSION FROM SHORT-LIVED CORE-HOLE STATES - THEORY AND APPLICATIONS FOR THE WATER MOLECULE
CESAR, A
AGREN, H
CARRAVETTA, V
[J]. PHYSICAL REVIEW A, 1989, 40 (01): : 187 - 206
[5] Quantifying hydrogen bond cooperativity in water: VRT spectroscopy of the water tetramer
Cruzan, JD
Braly, LB
Liu, K
Brown, MG
Loeser, JG
Saykally, RJ
[J]. SCIENCE, 1996, 271 (5245) : 59 - 62
[6] Is the hydrogen bond in water dimer and ice covalent?
Ghanty, TK
Staroverov, VN
Koren, PR
Davidson, ER
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (06) : 1210 - 1214
[7] INVESTIGATION OF THE ELECTRONIC-STRUCTURE OF ICE BY HIGH-RESOLUTION X-RAY SPECTROSCOPY
GILBERG, E
HANUS, MJ
FOLTZ, B
[J]. JOURNAL OF CHEMICAL PHYSICS, 1982, 76 (10) : 5093 - 5097
[8] Resonant x-ray emission spectroscopy of molecular oxygen
Glans, P
Gunnelin, K
Skytt, P
Guo, JH
Wassdahl, N
Nordgren, J
Agren, H
Gelmukhanov, FK
Warwick, T
Rotenberg, E
[J]. PHYSICAL REVIEW LETTERS, 1996, 76 (14) : 2448 - 2451
[9] Resonant and nonresonant x-ray scattering spectra of some poly(phenylenevinylene)s
Guo, JH
Magnuson, M
Såthe, C
Nordgren, J
Yang, L
Luo, Y
Ågren, H
Xing, KZ
Johansson, N
Salaneck, WR
Daik, R
Feast, WJ
[J]. JOURNAL OF CHEMICAL PHYSICS, 1998, 108 (14) : 5990 - 5996
[10] ELECTRONIC-STRUCTURE OF LA2-XSRXCUO4 STUDIED BY SOFT-X-RAY-FLUORESCENCE SPECTROSCOPY WITH TUNABLE EXCITATION
GUO, JH
BUTORIN, SM
WASSDAHL, N
SKYTT, P
NORDGREN, J
MA, Y
[J]. PHYSICAL REVIEW B, 1994, 49 (02): : 1376 - 1380

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