Isolation, structure elucidation, and absolute configuration of 26-deoxyactein from Cimicifuga racemosa and clarification of nomenclature associated with 27-deoxyactein

被引：86

作者：

Chen, SN

Li, WK

Fabricant, DS

Santarsiero, BD

Mesecar, A

Fitzloff, JF

Fong, HHS

Farnsworth, NR

机构：

[1] Univ Illinois, Coll Pharm, Dept Med Chem & Pharmacognosy, Program Collaborat Res Pharmaceut Sci MC877, Chicago, IL 60612 USA

[2] Univ Illinois, Ctr Pharmaceut Biotechnol MC 870, Chicago, IL 60612 USA

[3] Univ Illinois, Coll Pharm, UIC, NIH,Ctr Bot Dietary Supplements Res, Chicago, IL 60612 USA

来源：

JOURNAL OF NATURAL PRODUCTS | 2002年 / 65卷 / 04期

关键词：

D O I：

10.1021/np010494t

中图分类号：

Q94 [植物学];

学科分类号：

071001 ;

摘要：

A new triterpene glycoside, 26-deoxyactein (1), along with two known compounds, 23-epi-26-deoxyactein (2), previously designated as "27-deoxyactein", and actein (3), were isolated from the roots/rhizomes of Cimicifuga racemosa. The structures and absolute stereochemistry of 1 and 2 were established by spectroscopic methods (FABMS, H-1 and C-13 NMR) and single-crystal X-ray data analysis.

引用

页码：601 / 605

页数：5

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