Coinage metal complexes with N-heterocyclic carbene ligands as selective catalysts in diboration reaction

被引：88

作者：

Corberan, Rosa

Ramirez, Jesus

Poyatos, Macarena

Peris, Eduardo

Fernandez, Elena

机构：

[1] Univ Rovira & Virgili, Dpt Quim Fis & Inorgan, Tarragona 43007, Spain

[2] Univ Jaume 1, Dpt Quim Inorgan & Organ, Castellon de La Plana, Spain

来源：

TETRAHEDRON-ASYMMETRY | 2006年 / 17卷 / 12期

关键词：

D O I：

10.1016/j.tetasy.2006.06.027

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We describe the improved catalytic reactivity of terminal alkenes with 1,2-diboranes in the presence of Au(I) and Ag(I) complexes when N-heterocyclic carbene ligands are used. The new catalytic systems are able to diminish the undesired beta-H-elimination of the alkylboryl-metal intermediates, which leads to the formation of hydroborated byproducts. The electronic properties and the molecular structure of the precursors of the catalysts could explain the modest asymmetric induction provided. (c) 2006 Elsevier Ltd. All rights reserved.

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页码：1759 / 1762

页数：4

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