Interaction of interfacial convection and mass transfer effects in the system CO2-water

被引:55
作者
Arendt, B [1 ]
Dittmar, D [1 ]
Eggers, R [1 ]
机构
[1] Tech Univ Hamburg, Dept Thermal Separat Proc, D-21071 Hamburg, Germany
关键词
convection; natural convection; mass transfer;
D O I
10.1016/j.ijheatmasstransfer.2004.04.011
中图分类号
O414.1 [热力学];
学科分类号
摘要
The mass transfer of the system CO2-water was measured up to a pressure of 360 bar at a temperature of 25 degreesC and the results were compared to empirical predictions. The influence of a surfactant on the mass transfer was investigated. A Schlieren method and a three-mode magnetic suspension balance connected to an optical cell were used to analyse the mass transfer. A good simulation of the experimental values was achieved by linear superposition of free convection and Marangoni convection. The surfactant enforces the Marangoni convection while the solubility of CO2 stayed unaffected. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3649 / 3657
页数:9
相关论文
共 12 条
[1]  
Baehr D., 1998, HEAT MASS TRANSFER, DOI DOI 10.1007/978-3-642-20021-2
[2]  
BETZ J, 1997, STROMUNG WARMEUBERGA
[3]  
DOCTER A, 1997, FORTSCHRITT BERICH 3, V494
[4]   INTERFACIAL TURBULENCE DURING THE PHYSICAL ABSORPTION OF CARBON-DIOXIDE INTO NON-AQUEOUS SOLVENTS [J].
HOZAWA, M ;
KOMATSU, N ;
IMAISHI, N ;
FUJINAWA, K .
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1984, 17 (02) :173-179
[5]  
KLEINRAHM R, 1984, FORTSCHRITT BERICH 3, V92
[6]  
LOSCH HW, 1987, FORTSCHRITT BERICH 3, V138
[7]  
MAYINGER F, 2001, HEAT MASS TRANSFER O
[8]   Schlieren visualization of natural convection in binary gas-liquid systems [J].
Okhotsimskii, A ;
Hozawa, M .
CHEMICAL ENGINEERING SCIENCE, 1998, 53 (14) :2547-+
[9]  
Settles G. S, 2001, EXP FLUID MECH
[10]   INTERFACIAL TURBULENCE - HYDRODYNAMIC INSTABILITY AND THE MARANGONI EFFECT [J].
STERNLING, CV ;
SCRIVEN, LE .
AICHE JOURNAL, 1959, 5 (04) :514-523