Graphene quantum dots as sensor for phenols in olive oil

被引:57
作者
Benitez-Martinez, Sandra [1 ]
Valcarcel, Miguel [1 ]
机构
[1] Univ Cordoba, Dept Analyt Chem, E-14071 Cordoba, Spain
关键词
Graphene quantum dots; Sensor; Total phenols; Fluorescence quenching; Liquid-liquid extraction; Olive oil; CARBON NANOTUBES; HYDROTHERMAL SYNTHESIS; UP-CONVERSION; FLUORESCENCE; SURFACE; WATER; BLUE; PHOTOLUMINESCENCE; FIBERS; GREEN;
D O I
10.1016/j.snb.2014.03.008
中图分类号
O65 [分析化学];
学科分类号
070302 [分析化学];
摘要
A new method for the determination of the phenol fraction of olive oil is reported. An optical nanosensor based on graphene quantum dots, obtained by pyrolysis of citric acid, was specifically developed for this purpose. The ensuing fluorescence sensing method, which is simple, and highly sensitive and reproducible, was used here to determine gallic acid and oleuropein as model analytes commonly found in olive oils, as well as the phenolic concentration of olive oil real samples. The detection limits were lower than 0.12 mg L-1 and the precision, expressed as relative standard deviation, lower than 1.7%. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:350 / 357
页数:8
相关论文
共 35 条
[1]
GRAPHENE [J].
Brody, Herb .
NATURE, 2012, 483 (7389) :S29-S29
[2]
Carrasco-Pancorbo A., 2005, J SEP SCI, V28, P83
[3]
Strong luminescence of Carbon Dots induced by acetone passivation: Efficient sensor for a rapid analysis of two different pollutants [J].
Cayuela, Angelina ;
Soriano, M. Laura ;
Valcarcel, Miguel .
ANALYTICA CHIMICA ACTA, 2013, 804 :246-251
[4]
Blue luminescent graphene quantum dots and graphene oxide prepared by tuning the carbonization degree of citric acid [J].
Dong, Yongqiang ;
Shao, Jingwei ;
Chen, Congqiang ;
Li, Hao ;
Wang, Ruixue ;
Chi, Yuwu ;
Lin, Xiaomei ;
Chen, Guonan .
CARBON, 2012, 50 (12) :4738-4743
[5]
Graphene Quantum Dot as a Green and Facile Sensor for Free Chlorine in Drinking Water [J].
Dong, Yongqiang ;
Li, Geli ;
Zhou, Nana ;
Wang, Ruixue ;
Chi, Yuwu ;
Chen, Guonan .
ANALYTICAL CHEMISTRY, 2012, 84 (19) :8378-8382
[6]
One-step and high yield simultaneous preparation of single- and multi-layer graphene quantum dots from CX-72 carbon black [J].
Dong, Yongqiang ;
Chen, Congqiang ;
Zheng, Xinting ;
Gao, Lili ;
Cui, Zhiming ;
Yang, Hongbin ;
Guo, Chunxian ;
Chi, Yuwu ;
Li, Chang Ming .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (18) :8764-8766
[7]
Direct Synthesis of Graphene Quantum Dots by Chemical Vapor Deposition [J].
Fan, Lili ;
Zhu, Miao ;
Lee, Xiao ;
Zhang, Rujing ;
Wang, Kunlin ;
Wei, Jinquan ;
Zhong, Minlin ;
Wu, Dehai ;
Zhu, Hongwei .
PARTICLE & PARTICLE SYSTEMS CHARACTERIZATION, 2013, 30 (09) :764-769
[8]
Fluorescence resonance energy transfer quenching at the surface of graphene quantum dots for ultrasensitive detection of TNT [J].
Fan, Lishuang ;
Hu, Yuwei ;
Wang, Xiao ;
Zhang, Linlin ;
Li, Fenghua ;
Han, Dongxue ;
Li, Zhenggang ;
Zhang, Qixian ;
Wang, Zhenxin ;
Niu, Li .
TALANTA, 2012, 101 :192-197
[9]
Colloidal Graphene Quantum Dots [J].
Li, Liang-shi ;
Yan, Xin .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2010, 1 (17) :2572-2576
[10]
A Facile Microwave Avenue to Electrochemiluminescent Two-Color Graphene Quantum Dots [J].
Li, Ling-Ling ;
Ji, Jing ;
Fei, Rong ;
Wang, Chong-Zhi ;
Lu, Qian ;
Zhang, Jian-Rong ;
Jiang, Li-Ping ;
Zhu, Jun-Jie .
ADVANCED FUNCTIONAL MATERIALS, 2012, 22 (14) :2971-2979